Optical chemical sensors have been around for a number of years. Hundreds of molecular probes have been developed in organic and inorganic chemistry labs worldwide, spectroscopically and photochemically characterized, and applied to (bio)analytical methods development. Surprisingly enough, devices based on such chemosensory are still not widespread in the market arena [1]. A plethora of excitation wavelengths and light sources, optical phenomena (absorption, reflectance, luminescence, SPR, interferometry, …) and detection schemes make it difficult to find sufficiently general instrumentation to challenge the predominance of electrochemical sensors. However, this scenario changes dramatically if a family of indicator dyes (of luminescent nature for maximum sensitivity) are developed to be interrogated with a single optoelectronic unit and ready-to-change sensing layers.
Such a goal has been realized in my Group over more than 20 years with molecularly engineered luminescent Ru(II) complexes and exploiting their rich, tunable photophysics (excited state sensitivity, ESS) and photochemistry (energy, proton or electron transfer, abbreviated ENT, PT, ELT) [2]. In this tutorial I will be guiding the attendees on a trip about how challenges in industrial chemical optosensing can be tackled with tailored indicator dyes and a dedicated (portable) interrogation unit to measure dissolved O2, biological oxygen demand and waterborne herbicides (ENT); pH, CO2 and NH3 (PT); H2S and mercaptans (ELT); humidity (ESS); heavy metal ions (ELT); hydrocarbons (ESS) and temperature (ESS), among other species.In addition to on-line water quality monitoring (biological oxygen demand in WWTP depicted), the luminescent chemosensors are also being applied to on-board aircraft hydraulic fluid assessment, biomethane quality assurance, bioprocess monitoring and geotextile-embedded environmental sensing, among other applications [1, 3-5].
[1] G. Orellana, C. Cano-Raya, J. López-Gejo, A.R. Santos, “Online Monitoring Sensors”, in P. Wilderer (Ed.), Treatise on Water Science, vol. 3, Oxford: Academic Press, 2011; pp. 221–262.
[2] G. Orellana, D. García-Fresnadillo, in Optical Sensors: Industrial, Environmental and Diagnostic Applications, Springer Ser. Chem. Sens. and Biosens. Vol. 1, R. Naranayaswamy, O.S. Wolfbeis (Eds.), Springer, 2004; pp. 309–357.
[3] G. Orellana, J. López-Gejo, B. Pedras, "Silicone Films for Fiber-Optic Chemical Sensing", in A. Tiwari, M.D. Soucek (Eds.), Concise Encyclopedia of High Performance Silicones, Wiley-Scrivener, 2014; pp. 339–354.
[4] I. Urriza-Arsuaga, G. Ielasi, M. Bedoya, G. Orellana, “Luminescence-Based Sensors for Bioprocess Applications”, in B. Pedras (Ed.), Fluorescence in Industry, Springer Nature, 2019; pp. 1−38.
[5] B. Pedras, G. Orellana, M. N. Berberan-Santos, “Luminescence-Based Sensors for Aeronautical Applications”, in B. Pedras (Ed.), Fluorescence in Industry, Springer Nature, 2019; pp. 389−412.